Most raw materials are useful forever esp assuming you build new homes from time to time.
a few are not.. ancient wood, silver come to mind as about useless after a while.

every biome has useful consumed stuff to farm so you will revisit them, though.
Wolf meat from the mountains, and obsidian for arrows.
coal, iron, slime, bloodbags, guts and such from the swamp
blueberry, thistle, dwarf eyes, wood/rock/resin, from forest
admittedly the meadows isnt great. Berries and boar meat, I guess are always a little useful.